◎研究方向 1.均相催化,构建新型双功能配体以及过渡金属催化剂,并应用于羰基合成; 2.单原子催化,制备新型单原子催化剂,催化简单的有机反应。 ◎学习与工作经历 2010.9-2014.7,华东师范大学,化学与分子工程学院,应用化学专业,理学学士; 2014.9-2019.7,华东师范大学,化学与分子工程学院,物理化学专业,理学博士; 2019.7-2021.10,中国石油大学(华东),化学博士后流动站师资博士后; 2021.11至今,中国石油大学(华东),化学系,特任副教授。
◎指导研究生 协助指导硕士研究生2名。
◎承担和参与项目 1.近年来,主持的代表性科研项目: (1)“叔膦-季鏻鎓Lewis酸”双功能配体修饰的Ru定向催化胺与合成气的甲基化反应研究,国家自然科学基金青年项目,2022-2024。 (2)三功能钌催化剂共催化“氢甲酰化-羟醛缩合-加氢”反应,中国博士后科学基金面上项目二等资助,2019-2021。 (3)钌催化剂在氢甲酰化串联反应中的应用,自主创新科研计划项目(理工科),2019-2021。 2.近年来,参与的代表性科研项目: (1)缺陷诱导下绿色高效低成本多级孔分子筛的因势构筑与催化应用,国家自然科学基金面上项目,2022-2025。
(2)基于“叔膦-季鏻鎓”双功能配体“配位法”构建的双功能Ir(I)配合物催化CO2为羰基源的a-烯烃羰化酯化反应研究,国家自然科学基金面上项目,2020-2023。 ◎论文 1.第一作者主要论文: (1)Co-catalysis for hydroamidocarbonylation of alkynes with amides over a bifunctional ligand-based Pd catalyst,Chem Asian J., 2021, 16, 1-6. (2)Co-catalysis over bi-functional ligand based Ir-catalyst for tandem hydroformylation-acetalization reaction, Acta Chim. Sinica, 2021, 79, 658-662. (3)Co-catalysis over a tri-functional ligand modified Pd-catalyst for hydroxycarbonylation of terminal alkynes towards α,β-unsaturated carboxylic acids, Green Chem., 2019, 21, 5336-5344.
(4)Novel multi-dentate phosphines for Pd-catalyzed alkoxycarbonylation of alkynes promoted by H2O additive, J. Catal., 2019, 371, 236–244. (5)Co-catalysis over a bi-functional ligand-based Pd-catalyst for tandem bis-alkoxycarbonylation of terminal alkynes, Green Chem., 2018, 20, 2588-2595. (6)Au-complex containing phosphino and imidazolyl moieties as a bi-functional catalyst for one-pot synthesis of pyridine derivatives, J. Mol. Catal. A- Chem., 2016, 424, 323–330. (7)Ionic palladium complex as an efficient and recyclable catalyst for the carbonylative Sonogashira reaction, Chin. J. Catal., 2016, 37, 405–411. 2.第二作者(通讯作者)主要论文: (1)Novel Ir-complexes for hydroformylation of olefins with H2O as the hydrogen source,Chin. J. Org. Chem., 2021, 41, 3571-3577. (2)Recent advances on the synthesis of β-lactams by involving carbon monoxide, Chin. J. Org. Chem., 2021, 41, 3448-3458. (3)An efficient and recyclable ionic diphosphine-based Ir-catalyst for hydroaminomethylation of olefins with H2O as the hydrogen source, Chem. Commun., 2018, 54, 7979-7982. ◎专利 1.一种琥珀酸二酯或琥珀酸二酯衍生物的制备方法,ZL201711178172.8,2017年。 |